The Tunnel Effect in Chemistry

Nonfiction, Science & Nature, Science, Chemistry, Physical & Theoretical
Cover of the book The Tunnel Effect in Chemistry by Ronald Percy Bell, Springer US
View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart
Author: Ronald Percy Bell ISBN: 9781489928917
Publisher: Springer US Publication: November 11, 2013
Imprint: Springer Language: English
Author: Ronald Percy Bell
ISBN: 9781489928917
Publisher: Springer US
Publication: November 11, 2013
Imprint: Springer
Language: English

The suggestion that quantum-mechanical tunnelling might be a significant factor in some chemical reactions was first made fifty years ago by Hund, very soon after the principles of wave mechanics had been established by de Broglie, Schrodinger and Heisenberg, and similar ideas were put forward during the following thirty years by a number of authors. It was realised from the beginning that such effects would be particularly prominent in reactions involving the movement of protons or hydrogen atoms, and both theoretical and experimental work received a powerful stimulus in the discovery of deuterium in 1932. During the last twenty years theoretical predictions about the tunnel effect have been supported by an increasing body of experimental evidence, derived especially from studies of hydrogen isotope effects. The present book presents an attempt to summarize this evidence and to indicate the main lines of the basic theory. Details of mathematical manipuĀ­ lation are restricted mainly to Chapter 2 and the Appendices, and many readers may prefer to confine themselves to the results obtained. The main emphasis has been on the kinetics of chemical reactions involving the transfer of protons, hydrogen atoms or hydride ions, although Chapter 6 gives an account of the role of the tunnel effect in molecular spectra, and Chapter 7 makes some mention of tunnelling in solid state phenomena, biological processes and the electrolytic discharge of hydrogen. Only passing references have been made to tunnelling by electrons.

View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart

The suggestion that quantum-mechanical tunnelling might be a significant factor in some chemical reactions was first made fifty years ago by Hund, very soon after the principles of wave mechanics had been established by de Broglie, Schrodinger and Heisenberg, and similar ideas were put forward during the following thirty years by a number of authors. It was realised from the beginning that such effects would be particularly prominent in reactions involving the movement of protons or hydrogen atoms, and both theoretical and experimental work received a powerful stimulus in the discovery of deuterium in 1932. During the last twenty years theoretical predictions about the tunnel effect have been supported by an increasing body of experimental evidence, derived especially from studies of hydrogen isotope effects. The present book presents an attempt to summarize this evidence and to indicate the main lines of the basic theory. Details of mathematical manipuĀ­ lation are restricted mainly to Chapter 2 and the Appendices, and many readers may prefer to confine themselves to the results obtained. The main emphasis has been on the kinetics of chemical reactions involving the transfer of protons, hydrogen atoms or hydride ions, although Chapter 6 gives an account of the role of the tunnel effect in molecular spectra, and Chapter 7 makes some mention of tunnelling in solid state phenomena, biological processes and the electrolytic discharge of hydrogen. Only passing references have been made to tunnelling by electrons.

More books from Springer US

Cover of the book Low-Power Variation-Tolerant Design in Nanometer Silicon by Ronald Percy Bell
Cover of the book The Mental Health Consequences of Torture by Ronald Percy Bell
Cover of the book Environmental Tracers in Subsurface Hydrology by Ronald Percy Bell
Cover of the book Strategic Decisions by Ronald Percy Bell
Cover of the book A Psycholinguistic Perspective on Finnish and Japanese Prosody by Ronald Percy Bell
Cover of the book Water Development and Poverty Reduction by Ronald Percy Bell
Cover of the book Issues in Supportive Care of Cancer Patients by Ronald Percy Bell
Cover of the book Environmental Problems of the City Centres by Ronald Percy Bell
Cover of the book Vacuum Microbalance Techniques by Ronald Percy Bell
Cover of the book Real and Convex Analysis by Ronald Percy Bell
Cover of the book Strategic Human Resource Planning Applications by Ronald Percy Bell
Cover of the book Successful Aging by Ronald Percy Bell
Cover of the book Social Influence Processes and Prevention by Ronald Percy Bell
Cover of the book Current Topics in Primate Vocal Communication by Ronald Percy Bell
Cover of the book EMI/EMC Computational Modeling Handbook by Ronald Percy Bell
We use our own "cookies" and third party cookies to improve services and to see statistical information. By using this website, you agree to our Privacy Policy