The Pauson-Khand Reaction

Scope, Variations and Applications

Nonfiction, Science & Nature, Science, Chemistry, Physical & Theoretical
Cover of the book The Pauson-Khand Reaction by Ramon Rios Torres, Wiley
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Author: Ramon Rios Torres ISBN: 9781118308639
Publisher: Wiley Publication: March 1, 2012
Imprint: Wiley Language: English
Author: Ramon Rios Torres
ISBN: 9781118308639
Publisher: Wiley
Publication: March 1, 2012
Imprint: Wiley
Language: English

The Pauson-Khand reaction is an important reaction in the field of organic chemistry. It involves the transition-metal catalysed cycloaddition of an alkyne, an alkene and carbon monoxide, to produce cyclopentenones. The importance of this reaction originates from its high value in transforming simple components into the synthetically useful cyclopentenone unit, in which a high degree of molecular complexity can be achieved in a single step, with impressive stereochemical and regiochemical control.

The Pauson-Khand Reaction investigates the nature and many variations of this reaction.

Topics covered include:

  • the mechanisms of Pauson‐Khand-type reactions
  • non chiral intramolecular and intermolecular versions of Pauson‐Khand reactions
  • asymmetric Pauson‐Khand reaction using chiral auxiliaries
  • the enantioselective Pauson‐Khand reaction
  • Pauson‐Khand reactions catalysed by metals other than cobalt
  • unconventional Pauson‐Khand reactions
  • the Pauson‐Khand reaction in total synthesis

Presenting a comprehensive overview of this fundamental reaction, The Pauson-Khand Reaction will find a place on the bookshelves of any organic or organometallic chemist.

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The Pauson-Khand reaction is an important reaction in the field of organic chemistry. It involves the transition-metal catalysed cycloaddition of an alkyne, an alkene and carbon monoxide, to produce cyclopentenones. The importance of this reaction originates from its high value in transforming simple components into the synthetically useful cyclopentenone unit, in which a high degree of molecular complexity can be achieved in a single step, with impressive stereochemical and regiochemical control.

The Pauson-Khand Reaction investigates the nature and many variations of this reaction.

Topics covered include:

Presenting a comprehensive overview of this fundamental reaction, The Pauson-Khand Reaction will find a place on the bookshelves of any organic or organometallic chemist.

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