Sulfur Dioxide Insertion Reactions for Organic Synthesis

Nonfiction, Science & Nature, Science, Chemistry, Clinical, Organic
Cover of the book Sulfur Dioxide Insertion Reactions for Organic Synthesis by Danqing Zheng, Jie Wu, Springer Singapore
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Author: Danqing Zheng, Jie Wu ISBN: 9789811042027
Publisher: Springer Singapore Publication: April 4, 2017
Imprint: Springer Language: English
Author: Danqing Zheng, Jie Wu
ISBN: 9789811042027
Publisher: Springer Singapore
Publication: April 4, 2017
Imprint: Springer
Language: English

This brief summarizes the most commonly used sulfur dioxide surrogates and also shows the diverse reactivities to highlight the advances made in the development of synthetic methods through the insertion of sulfur dioxide. Depending on the nature of the transformation, these reactions are classified into four types: (i) pericyclic reactions; (ii) nucleophilic addition with organometallic reagents; (iii) transition metal catalysis; and (iv) free radical reactions.

Highlighting recent advances in the insertion of sulfur dioxide, providing detailed descriptions of the experimental procedures for these valuable reactions, and discussing the remaining challenges in this field, the brief offers an appealing and highly useful guide for a wide readership in organic chemistry and medicinal chemistry from both academia and industry.

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This brief summarizes the most commonly used sulfur dioxide surrogates and also shows the diverse reactivities to highlight the advances made in the development of synthetic methods through the insertion of sulfur dioxide. Depending on the nature of the transformation, these reactions are classified into four types: (i) pericyclic reactions; (ii) nucleophilic addition with organometallic reagents; (iii) transition metal catalysis; and (iv) free radical reactions.

Highlighting recent advances in the insertion of sulfur dioxide, providing detailed descriptions of the experimental procedures for these valuable reactions, and discussing the remaining challenges in this field, the brief offers an appealing and highly useful guide for a wide readership in organic chemistry and medicinal chemistry from both academia and industry.

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