Organotrifluoroborate Preparation, Coupling and Hydrolysis

Nonfiction, Science & Nature, Science, Chemistry, Organic, Technical & Industrial
Cover of the book Organotrifluoroborate Preparation, Coupling and Hydrolysis by Alastair J. J. Lennox, Springer International Publishing
View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart
Author: Alastair J. J. Lennox ISBN: 9783319011349
Publisher: Springer International Publishing Publication: August 13, 2013
Imprint: Springer Language: English
Author: Alastair J. J. Lennox
ISBN: 9783319011349
Publisher: Springer International Publishing
Publication: August 13, 2013
Imprint: Springer
Language: English

Alistair Lennox's thesis reports on the reactivity of organotrifluoroborates, which are becoming increasingly important reagents in synthesis. The thesis is divided into three sections. The first section describes a method for preparing organotrifluoroborates. The second section reports on a mechanistic investigation into the main application of RBF3K reagents as coupling partners in Suzuki-Miyaura coupling, phenomena identified as arising from organotrifluoroborate hydrolysis and fluoride release. The final section reports on a detailed investigation into the hydrolysis mechanism, a prerequisite for their Suzuki-Miyaura coupling, and how it may be predicted and controlled. This research has uncovered many interesting and useful details and shows how problems associated with Suzuki-Miyaura coupling can best be addressed. There has already been wide industrial uptake of the new procedures and insights. The broad nature and clear and succinct style will make the thesis a valuable resource for anyone working in synthesis, organometallic chemistry, or in homogeneous catalysis.

View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart

Alistair Lennox's thesis reports on the reactivity of organotrifluoroborates, which are becoming increasingly important reagents in synthesis. The thesis is divided into three sections. The first section describes a method for preparing organotrifluoroborates. The second section reports on a mechanistic investigation into the main application of RBF3K reagents as coupling partners in Suzuki-Miyaura coupling, phenomena identified as arising from organotrifluoroborate hydrolysis and fluoride release. The final section reports on a detailed investigation into the hydrolysis mechanism, a prerequisite for their Suzuki-Miyaura coupling, and how it may be predicted and controlled. This research has uncovered many interesting and useful details and shows how problems associated with Suzuki-Miyaura coupling can best be addressed. There has already been wide industrial uptake of the new procedures and insights. The broad nature and clear and succinct style will make the thesis a valuable resource for anyone working in synthesis, organometallic chemistry, or in homogeneous catalysis.

More books from Springer International Publishing

Cover of the book Cloud Computing and Services Science by Alastair J. J. Lennox
Cover of the book Cross-Cultural Design. Applications in Cultural Heritage, Creativity and Social Development by Alastair J. J. Lennox
Cover of the book Stochastic Analysis for Poisson Point Processes by Alastair J. J. Lennox
Cover of the book Performance Phenomenology by Alastair J. J. Lennox
Cover of the book Intelligent Data Engineering and Automated Learning – IDEAL 2015 by Alastair J. J. Lennox
Cover of the book AIDA-CMK: Multi-Algorithm Optimization Kernel Applied to Analog IC Sizing by Alastair J. J. Lennox
Cover of the book Nothing To Come by Alastair J. J. Lennox
Cover of the book Testbeds and Research Infrastructures for the Development of Networks and Communities by Alastair J. J. Lennox
Cover of the book Religious Ethics in the Market Economy by Alastair J. J. Lennox
Cover of the book Intelligent Systems Design and Applications by Alastair J. J. Lennox
Cover of the book Visually Observing Comets by Alastair J. J. Lennox
Cover of the book Short Course Breast Radiotherapy by Alastair J. J. Lennox
Cover of the book A First Introduction to the Finite Element Analysis Program MSC Marc/Mentat by Alastair J. J. Lennox
Cover of the book Disability and Vocational Rehabilitation in Rural Settings by Alastair J. J. Lennox
Cover of the book Domestication of Radiata Pine by Alastair J. J. Lennox
We use our own "cookies" and third party cookies to improve services and to see statistical information. By using this website, you agree to our Privacy Policy