Milestones in Microwave Chemistry

Nonfiction, Science & Nature, Science, Chemistry, Technical & Industrial, Organic
Cover of the book Milestones in Microwave Chemistry by , Springer International Publishing
View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart
Author: ISBN: 9783319306322
Publisher: Springer International Publishing Publication: March 22, 2016
Imprint: Springer Language: English
Author:
ISBN: 9783319306322
Publisher: Springer International Publishing
Publication: March 22, 2016
Imprint: Springer
Language: English

This book looks back on thirty-five years of microwave (MW) chemistry and explains how the application of the MW technique became an integral part of R&D, eventually becoming recognized in industry. Further, it details how MW chemistry has undergone a dynamic development in the past three decades, one driven by the advent of increasingly sophisticated professional MW reactors in place of the kitchen MW ovens used in earlier years. A major part of the book shows how substitutions, esterifications, amidations, hydrolyses, alkylations, eliminations, dehydrations, condensations, cyclizations, C–C couplings and the modification of heterocycles can be performed advantageously under MW irradiation, as the reaction times are shorter, while the selectivity and yields are higher; it also explains why in most cases, the reactions can be performed under solvent-free conditions. MW irradiation within the sphere of organophosphorus chemistry is showcased and typical reactions, such as the direct derivatization of phosphinic acids, alkylating esterifications, Diels–Alder reactions, the inverse Wittig-type reaction, fragmentations, the Arbuzov reaction, the synthesis of α-hydroxyphosphonates and α-aminophosphonates (the Kabachnik–Fields condensation), deoxygenations and P–C coupling reactions are described under MW conditions. In closing, the advantages of MW chemistry such as faster reactions and the possibility of simplifying the catalytic systems are addressed.

View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart

This book looks back on thirty-five years of microwave (MW) chemistry and explains how the application of the MW technique became an integral part of R&D, eventually becoming recognized in industry. Further, it details how MW chemistry has undergone a dynamic development in the past three decades, one driven by the advent of increasingly sophisticated professional MW reactors in place of the kitchen MW ovens used in earlier years. A major part of the book shows how substitutions, esterifications, amidations, hydrolyses, alkylations, eliminations, dehydrations, condensations, cyclizations, C–C couplings and the modification of heterocycles can be performed advantageously under MW irradiation, as the reaction times are shorter, while the selectivity and yields are higher; it also explains why in most cases, the reactions can be performed under solvent-free conditions. MW irradiation within the sphere of organophosphorus chemistry is showcased and typical reactions, such as the direct derivatization of phosphinic acids, alkylating esterifications, Diels–Alder reactions, the inverse Wittig-type reaction, fragmentations, the Arbuzov reaction, the synthesis of α-hydroxyphosphonates and α-aminophosphonates (the Kabachnik–Fields condensation), deoxygenations and P–C coupling reactions are described under MW conditions. In closing, the advantages of MW chemistry such as faster reactions and the possibility of simplifying the catalytic systems are addressed.

More books from Springer International Publishing

Cover of the book Systems for Drug Delivery by
Cover of the book Lateral Power Transistors in Integrated Circuits by
Cover of the book Basic Techniques for Extremity Reconstruction by
Cover of the book Impact of Culture on Management of Foreign SMEs in China by
Cover of the book Physics of Tsunamis by
Cover of the book Unconventional Water Resources and Agriculture in Egypt by
Cover of the book Differential Equations of My Young Years by
Cover of the book The Role of Submarine Groundwater Discharge as Material Source to the Baltic Sea by
Cover of the book Putting Systems and Complexity Sciences Into Practice by
Cover of the book Chemistry of Polymeric Metal Chelates by
Cover of the book The Transnational Activist by
Cover of the book Anticoagulation and Hemostasis in Neurosurgery by
Cover of the book Software Engineering: Challenges and Solutions by
Cover of the book Underactive Bladder by
Cover of the book Sustainable Automotive Technologies 2013 by
We use our own "cookies" and third party cookies to improve services and to see statistical information. By using this website, you agree to our Privacy Policy