Chemical Transformations of Vinylidenecyclopropanes

Nonfiction, Science & Nature, Science, Chemistry, Technical & Industrial, Organic
Cover of the book Chemical Transformations of Vinylidenecyclopropanes by Lixiong Shao, Jianmei Lu, Min Shi, Springer Berlin Heidelberg
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Author: Lixiong Shao, Jianmei Lu, Min Shi ISBN: 9783642275739
Publisher: Springer Berlin Heidelberg Publication: January 10, 2012
Imprint: Springer Language: English
Author: Lixiong Shao, Jianmei Lu, Min Shi
ISBN: 9783642275739
Publisher: Springer Berlin Heidelberg
Publication: January 10, 2012
Imprint: Springer
Language: English

Modern organic synthesis has paid much attention to the chemistry of small carbocycles. Vinylidenecyclopropanes (VDCPs), which have strained cyclopropyl group connected with an allene moiety and yet are thermally stable and reactive substances in organic chemistry, are versatile intermediates in organic synthesis. In this volume, Dr. Lixiong Shao, Dr. Jianmei Lu and Prof. Dr. Min Shi review their investigations on the chemistry of VDCPs, mainly including the preparation, the reactivities upon treatment with Lewis or Brønsted acid, as well as transition metal catalysts and some other miscellaneous analogues. The contributions aroused a renaissance of cationic intermediates in the chemistry of VDCPs.

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Modern organic synthesis has paid much attention to the chemistry of small carbocycles. Vinylidenecyclopropanes (VDCPs), which have strained cyclopropyl group connected with an allene moiety and yet are thermally stable and reactive substances in organic chemistry, are versatile intermediates in organic synthesis. In this volume, Dr. Lixiong Shao, Dr. Jianmei Lu and Prof. Dr. Min Shi review their investigations on the chemistry of VDCPs, mainly including the preparation, the reactivities upon treatment with Lewis or Brønsted acid, as well as transition metal catalysts and some other miscellaneous analogues. The contributions aroused a renaissance of cationic intermediates in the chemistry of VDCPs.

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